column 7 of the hazardous materials table

Hazardous materials not necessary for the safe and proper operation of the cargo transport unit must not be transported within the cargo transport unit. 123 Any explosives, blasting, type C containing chlorates must be segregated from explosives containing ammonium nitrate or other ammonium salts. Packaging must be UN standard metal drums attached with heavy duty steel strapping to a pallet; and. (h) Column 7: Special provisions. Table I - Maximum Ambient Temperature - Gasoline. B90 Steel tanks conforming or equivalent to ASME specifications which contain solid or semisolid residual motor fuel antiknock mixture (including rust, scale, or other contaminants) may be shipped by rail freight or highway. Batteries contained in devices must be securely installed. If a vehicle is powered by a flammable liquid and a flammable gas internal combustion engine, it must be described using Vehicle, flammable gas powered. This includes hybrid electric vehicles powered by both an internal combustion engine and wet, sodium or lithium batteries installed. (TOY CAPS) - HANDLE CAREFULLY OR TOY CAPS - HANDLE CAREFULLY; and. 113 The sample must be given a tentative approval by an agency or laboratory in accordance with 173.56 of this subchapter. Except when the liquids are fully absorbed in solid material contained in sealed bags, for single packagings, each packaging must correspond to a design type that has passed a leakproofness test at the Packing Group II level. B65 Tank cars constructed before March 16, 2009, must have a test pressure of 34.47 Bar (500 psig) or greater and conform to Class 105A. Nickel-carbon asymmetric capacitors containing Class 8 alkaline electrolytes must be transported as UN2795, Batteries, wet, filled with alkali, electric storage. TP26 The heating device must be exterior to the shell. The requirements of 173.24(g)(1) and 173.27(c) do not apply. 53 Packages of these materials must bear the subsidiary risk label, EXPLOSIVE, and the subsidiary hazard class/division must be entered in parentheses immediately following the primary hazard class in the shipping description, unless otherwise provided in this subchapter or through an approval issued by the Associate Administrator, or the competent authority of the country of origin. N32 Aluminum materials of construction are not authorized for single packagings. Thickness of stainless steel for tank shell and heads must be the greater of 7.62 mm (0.300 inch) or the thickness required for a portable tank with a design pressure at least equal to 1.5 times the vapor pressure of the hazardous material at 46 C (115 F). N84 The maximum quantity per package is 500 g (1.1 lbs.). In addition, the portable tank must be designed so that internal surfaces may be effectively cleaned and passivated. 61 A chemical oxygen generator is spent if its means of ignition and all or a part of its chemical contents have been expended. The table below gives the various types of Lead alloy solders. 420 This entry does not apply to manufactured articles (such as table tennis balls). (1) Even though certain packagings are specified in this part, it is, nevertheless, the responsibility of the person offering a hazardous material for transportation to ensure that such packagings are compatible with their lading. that, for example, are used for medical, analytical, diagnostic, testing, or repair purposes. Special Provision Letter Codes Used in Hazmat Table, Column 7 Column 7 uses eight letter codes. B49 Tanks equipped with interior heater coils are not authorized. Each special provision is indicated using a numeric or alphanumeric code. The Code of Federal Regulations (CFR) is the official legal print publication containing the codification of the general and permanent rules published in the Federal Register by the departments and agencies of the Federal Government. 383 For transportation by motor vehicle, substances meeting the conditions for high viscosity flammable liquids as prescribed in 173.121(b)(1)(i), (b)(1)(ii), and (b)(1)(iv) of this subchapter, may be reassigned to Packing Group III under the following conditions: a. 22 If the hazardous material is in dispersion in organic liquid, the organic liquid must have a flash point above 50 C (122 F). However, the hazard label corresponding to the hazard class or division may be substituted for the marking. Amdt. N7 The hazard class or division number of the material must be marked on the package in accordance with 172.302 of this subchapter. 21 This material must be stabilized by appropriate means (e.g., addition of chemical inhibitor, purging to remove oxygen) to prevent dangerous polymerization (see 173.21(f) of this subchapter). Thickness of stainless steel for portable tank shells and heads must be the greater of 6.35 mm (0.250 inch) or the thickness required for a portable tank with a design pressure at least equal to 1.3 times the vapor pressure of the hazardous material at 46 C (115 F). Net weight of contents in fiberboard boxes may not exceed 29 kg (64 pounds). 115 Boosters with detonator, detonator assemblies and boosters with detonators in which the total explosive charge per unit does not exceed 25 g, and which will not mass detonate and undergo only limited propagation in the shipping package may be assigned to 1.4B classification code. information or personal data. and are not subject to requirements of this subchapter except for the following: (a) Incident reporting. For portable tanks used for the transport of refrigerated liquefied helium and refrigerated liquefied atmospheric gas (except oxygen), the maximum rate at which the tank is filled must not exceed the liquid flow capacity of the pressure relief device rated at 130 percent of the portable tank's design pressure. TP38 Each portable tank must be insulated with an insulating material so that the overall thermal conductance at 15.5 C (60 F) is no more than 1.5333 kilojoules per hour per square meter per degree Celsius (0.075 Btu per hour per square foot per degree Fahrenheit) temperature differential. Column 7 contains special provisions associated with the hazardous material. Displaying title 49, up to date as of 3/02/2023. A112 Notwithstanding the quantity limits shown in Column (9A) and (9B) for this entry, the following IBCs are authorized for transportation aboard passenger and cargo-only aircraft. (i) These provisions apply to the transportation of hazardous materials in IM and UN Specification portable tanks. A copy of the approval shall accompany the shipping papers. 74 During transport, this material must be protected from direct sunshine and stored or kept in a cool and well-ventilated place, away from all sources of heat. Each portable tank constructed of metal must be fitted with a pressure-relief device consisting of a reclosing spring loaded type, a frangible disc or a fusible element. Please do not provide confidential While columns 8 and 7 of the Hazardous Materials Table are used to determine authorized packaging for most HazMat (more on that in a little bit), some methods of transportation, HazMat quantities, and specific operations rely on other methods. B78 Tank cars must have a test pressure of 4.14 Bar (60 psig) or greater and conform to Class 103, 104, 105, 109, 111, 112, 114 or 120. 28 The dihydrated sodium salt of dichloroisocyanuric acid does not meet the criteria for inclusion in Division 5.1 (Oxidizer) and is not subject to the requirements of this subchapter unless meeting the criteria for inclusion in another class or division. N89 When steel UN pressure receptacles are used, only those bearing the H mark are authorized. It is not an official legal edition of the CFR. 2 This material is poisonous by inhalation (see 171.8 of this subchapter) in Hazard Zone B (see 173.116(a) or 173.133(a) of this subchapter), and must be described as an inhalation hazard under the provisions of this subchapter. 172 This entry includes alcohol mixtures containing up to 5% petroleum products. The cylinder must be transported in a closed motor vehicle displaying FLAMMABLE GAS placards in accordance with subpart F of part 172 of this subchapter. formatting. Table 3 authorizes Large Packagings for specific proper shipping names through the use of IB Codes assigned in the 172.101 table of this subchapter. 197 The nitrocellulose must meet the criteria of the Bergmann-Junk test or methyl violet paper test in the UN Manual of Tests and Criteria, Appendix 10 (IBR, see 171.7 of this subchapter). They will appear as a list of codes that are defined in 172.102 of the Code of Federal Regulations. B80 Each cargo tank must have a minimum design pressure of 276 kPa (40 psig). (7) Special Provisions (172.102) IB8, IP2, IP4 5. ); and. per pound of hydrogen peroxide solution. The material may only be loaded with Class 3, Class 8, and Division 4.1 materials in Packing Group II or III. 360 Vehicles powered only by lithium batteries must be described using UN3171, Battery-powered vehicle. Lithium batteries installed in a cargo transport unit, designed only to provide power external to the transport unit, must be described using UN3536, Lithium batteries installed in a cargo transport unit., 361 Capacitors with an energy storage capacity of 0.3 Wh or less are not subject to the requirements of this subchapter. B35 Tank cars containing hydrogen cyanide may be alternatively marked Hydrocyanic acid, liquefied if otherwise conforming to marking requirements in subpart D of this part. Retain a copy of each notification of pilot-in-command if requested for up to 30 days Which one of the following hazardous materials is NOT excepted from the quantity limitations in 175.75? (i) Tests must be performed on each type and size of bottle, for each manufacturing location. 49 Mixtures of solids that are not subject to this subchapter and corrosive liquids may be transported under this entry without first applying the classification criteria of Class 8, provided there is no free liquid visible at the time the material is loaded or at the time the packaging or transport unit is closed. Get the latest updates, news, and regulations for HazMat Transport and Waste Management. 146 This description may be used for a material that poses a hazard to the environment but does not meet the definition for a hazardous waste or a hazardous substance, as defined in 171.8 of this subchapter, or any hazard class, as defined in part 173 of this subchapter, if it is designated as environmentally hazardous by another Competent Authority. The tank car specification may be marked to indicate a test pressure of 20.68 Bar (300 psig). Use the navigation links in the gray bar above to view the table of contents that this content belongs to. Comparative fire testing between a package as prepared for transport (including the substance to be transported) and an identical package filled with water must show that the maximum temperature measured inside the packages during testing does not differ by more than 200 C (392 F). This entry may not be used for ammonium nitrate for which a proper shipping name already exists in the 172.101 Hazardous Materials Table, including ammonium nitrate mixed with fuel oil or any other commercial grade of ammonium nitrate (e.g., ammonium nitrate fertilizer). A metal hydride storage system installed in or intended to be installed in a vehicle or equipment or in vehicle or equipment components must be approved for transport by the Associate Administrator. Additionally, the offeror must notify the carrier if the tank pressure rise exceeds 3 psig over any 24-hour period. Size of marking on bulk package must conform to 172.302(b) of this subchapter. 386 When transported by private motor carrier only, the following corrosive liquids may be packaged in polyethylene bottles with a capacity no greater than 3.785 L (one gallon), further packed inside an open-top, heavy wall, high density polyethylene box (i.e., crate) in a manner that the polyethylene bottles are not subjected to any superimposed weight, and the boxes must be reasonably secured against shifting within the transport vehicle and loaded so as to minimize the possibility of coming in contact with other lading: Compounds, cleaning liquid, NA1760, PG II or III; Corrosive liquid, acidic, inorganic, n.o.s., UN3264, PG II; Corrosive liquid, acidic, organic, n.o.s., UN3265, PG III; Corrosive liquid, basic, inorganic, n.o.s., UN3266, PG II; Hydrochloric acid solution, UN1789, PG II; and. [Amdt. 52 This entry may only be used for substances that are too insensitive for acceptance into Class 1 (explosive) when tested in accordance with Test Series 2 in the UN Manual of Tests and Criteria, Part I (incorporated by reference; see 171.7 of this subchapter). 144 If transported as a residue in an underground storage tank (UST), as defined in 40 CFR 280.12, that has been cleaned and purged or rendered inert according to the American Petroleum Institute (API) Standard 1604 (IBR, see 171.7 of this subchapter), then the tank and this material are not subject to any other requirements of this subchapter. Using the nominal capacitance (CN), rated voltage (UR) and the rated lower limit voltage (UL). Filling limits must be in accordance with portable tank special provision TP3. The maximum degree of filling must not exceed the degree of filling determined by the following: tr is the maximum mean bulk temperature during transport, tf is the temperature in degrees celsius of the liquid during filling, and. If you work for a Federal agency, use this drafting B130 When transported by motor vehicle, used diatomaceous earth filter material is not subject to any other requirements of this subchapter except for the shipping paper requirements of subpart C of part 172 of this subchapter; emergency response information as required by 172.602(a)(2) through (a)(7) of this subchapter; and the marking requirements of 172.302 of this subchapter, if the following requirements are met: a. Packagings are non-DOT specification sift-proof motor vehicles or sift-proof roll-on/roll-off bulk bins, which are covered by a tarpaulin or other equivalent means. N88 Any metal part of a UN pressure receptacle in contact with the contents may not contain more than 65% copper, with a tolerance of 1%. A11 For combination packagings, when metal inner packagings are permitted, only specification cylinders constructed of metals which are compatible with the hazardous material may be used. Each Net weight of contents may not exceed 15 kg (33 pounds). (2) They must be packed in strong outer packagings and the completed package must be capable of withstanding a 1.8 meter (5.9 feet) drop without leakage of gas contents from detectors. 38 If this material shows a violent effect in laboratory tests involving heating under confinement, the labeling requirements of Special Provision 53 apply, and the material must be packaged in accordance with packing method OP6 in 173.225 of this subchapter. The total mass of lithium batteries contained in any package must not exceed the quantity limits in columns (9A) and (9B) for passenger aircraft or cargo aircraft, as applicable; b. Do not enter until vapors have dissipated. The driver of the transport vehicle and the consignee(s) must be trained not to enter the transport vehicle until the ammonia vapors have dissipated, and the emergency response information on the shipping paper must indicate that the vehicle contains ammonia vapors. Wall thickness must be verified ultrasonically at intervals midway between periodic hydraulic tests (every 2.5 years). Regulation Y (iii) A copy of the test results must be kept on file at each facility where packagings are offered for transportation, and must be made available to a representative of the Department upon request. (eg: 105 The word Agents may be used instead of Explosives when approved by the Associate Administrator. For transportation of new lighter design samples for examination and testing, see 173.308(b)(2). For example, nickel-metal hydride batteries transported by vessel in certain quantities are covered by another entry (see Batteries, nickel-metal hydride, UN3496). 1/1.1 Note also that this exception does not apply to batteries that have been reconditioned for reuse. Column 7 of the HMT specifies codes for special provisions applicable to packaging, packaging requirements, certification, and marking or labeling for a hazardous material. B132 Except for transportation by aircraft, UN2813, Water reactive solid, n.o.s. f. Chemicals under pressure containing components forbidden for transport on both passenger and cargo aircraft in Columns (9A) and (9B) of the 172.101 Hazardous Materials Table must not be transported by air. 46 This material must be packed in accordance with packing method OP6 (see 173.225 of this subchapter). Table 1 authorizes IBCs for specific proper shipping names through the use of IB Codes assigned in the 172.101 table of this subchapter. switch to drafting.ecfr.gov. However, button cell batteries installed in equipment (including circuit boards) need not be considered; and, c. The shipping paper must indicate UN 3091 Lithium metal batteries packed with equipment or UN 3481 Lithium ion batteries packed with equipment, as appropriate. The official, published CFR, is updated annually and available below under View the most recent official publication: These links go to the official, published CFR, which is updated annually. (2) To the extent a special provision imposes limitations or additional requirements on the packaging provisions set forth in column 8 of the 172.101 table, packagings must conform to the requirements of the special provision. 121 This substance, when containing less alcohol, water or phlegmatizer than specified, may not be transported unless approved by the Associate Administrator. Each transport unit must be leakproof when used as bulk packaging. The device must be in the vapor space when the tank is filled under maximum filling conditions. D. Class 5 materials (3) A code containing the letter B refers to a special provision that applies only to bulk packaging requirements. A lighter refill exceeding 4 fluid ounces capacity (7.22 cubic inches) or containing more than 65 grams of fuel must be classed as a Division 2.1 material, described with the proper shipping name appropriate for the material, and packaged in the packaging specified in part 173 of this subchapter for the flammable gas contained therein. d. Receptacles containing adsorbed or absorbed ammonia shall meet the following conditions: (1) Receptacles shall be made of a material compatible with ammonia as specified in ISO 11114-1:2012(E) and ISO 11114-1:2012/Amd 1:2017(E) (IBR, see 171.7 of this subchapter); (2) Receptacles and their means of closure shall be hermetically sealed and able to contain the generated ammonia; (3) Each receptacle shall be able to withstand the pressure generated at 85 C (185 F) with a volumetric expansion no greater than 0.1%; (4) Each receptacle shall be fitted with a device that allows for gas evacuation once pressure exceeds 15 bar (1500 kPa) without violent rupture, explosion or projection; and. (1) Numeric provisions. Alternatively, the item itself may be used as a packaging if it meets the general packaging requirements of subparts A and B of part 173 of this subchapter. 172.101 Hazardous Materials Table (HMT). Where the quantity of hazardous materials contained as an integral element in machinery or apparatus exceeds the limits permitted by 173.222(c)(2), and the hazardous materials meet the provisions of 173.222(c), the machinery or apparatus may be transported by aircraft only with the prior approval of the Associate Administrator. The packing group assignment and packaging must be approved by the Associate Administrator for Hazardous Materials Safety on the basis of the criteria in 173.21 of this subchapter and the package type used for the Series 6(c) test. B44 All parts of valves and safety relief devices in contact with lading must be of a material which will not cause formation of acetylides. Example: Yes, I would like to receive emails from Daniels Training Services. 150 This description may only be used for ammonium nitrate-based fertilizers. An unused lighter or a lighter that is cleaned of residue and purged of vapors is not subject to the requirements of this subchapter. You are using an unsupported browser. 162 This material may be transported under the provisions of Division 4.1 only if it is packed so that at no time during transport will the percentage of diluent fall below the percentage that is stated in the shipping description. A13 Bulk packagings are not authorized for transportation by aircraft. c. A composite packaging 6PG2 (glass, porcelain or stoneware receptacles within a fiberboard box). b. 45 Temperature should be maintained between 18 C (64.4 F) and 40 C (104 F). 78 This entry may not be used to describe compressed air which contains more than 23.5 percent oxygen. The receptacle must contain no hazardous materials other than the liquid nitrogen which must be fully absorbed in a porous material in the receptacle. N91 The use of a non specification sift-proof, non-bulk, metal can with or without lid, or a non specification sift-proof, non-bulk fiber drum, with or without lid is authorized when transporting coal tar pitch compounds by motor vehicle or rail freight. Bulk outer packagings must be liquid tight through design or by the use of lining materials. This molecular arrangement is exactly the same as that for dithioketo QA [5]. As a 54 Maneb or maneb preparations not meeting the definition of Division 4.3 or any other hazard class are not subject to the requirements of this subchapter when transported by motor vehicle, rail car, or aircraft. The material is also be subject to operational controls which include not exceeding a temperature of 55C (130F) at the time it is offered or during transportation, not exceeding a transportation time of 24 hours, and drivers transporting spent bleaching earth must be trained in the properties and hazards of the spent bleaching earth. The operator of an aircraft carrying hazardous materials must do all of the following EXCEPT: A. B13 A nonspecification cargo tank motor vehicle authorized in 173.247 of this subchapter must be at least equivalent in design and in construction to a DOT 406 cargo tank or MC 306 cargo tank (if constructed before August 31, 1995), except as follows: a. Packagings equivalent to MC 306 cargo tanks are excepted from the certification, venting, and emergency flow requirements of the MC 306 specification. (3) A flammable gas is a gas that meets the criteria in 173.115 of this subchapter. No Class 7 label is required to be displayed. The articles may be transported as in Division 1.4 Compatibility Group D (1.4D) if all of the conditions specified in 173.63(a) of this subchapter are met. Packagings of other material constructed with a small amount of metal must be designed such that the hazardous material does not contact the metal. If chemical stabilization becomes ineffective at lower temperatures within the anticipated duration of transport, temperature control is required and is forbidden by aircraft. TP44 Each portable tank must be made of stainless steel, except that steel other than stainless steel may be used in accordance with the provisions of 173.24b(b) of this subchapter. b. Choosing an item from In addition to meeting the conditions in this provision, transport on cargo aircraft only may be authorized with prior approval of the Associate Administrator. e. When offered for transport in an ammonia dispenser, the receptacles shall be connected to the dispenser in such a way that the assembly is guaranteed to have the same strength as a single receptacle. When Column 7 refers to a special provision for a hazardous material, the meaning and requirements of that special provision are as set forth in 172.102 of this subpart. Nickel-metal hydride batteries subject to this special provision are subject only to the following requirements: (1) The batteries must be prepared and packaged for transport in a manner to prevent a dangerous evolution of heat, short circuits, and damage to terminals; and are subject to the incident reporting in accordance with 171.16 of this subchapter if a fire, violent rupture, explosion or dangerous evolution of heat (i.e., an amount of heat sufficient to be dangerous to packaging or personal safety to include charring of packaging, melting of packaging, scorching of packaging, or other evidence) occurs as a direct result of a nickel metal hydride battery; and (2) when loaded in a cargo transport unit in a total quantity of 100 kg gross mass or more, the shipping paper requirements of Subpart C of this part, the manifest requirements of 176.30 of this subchapter, and the vessel stowage requirements assigned to this entry in Column (10) of the 172.101 Hazardous Materials Table. For UN2031 with more than 55% nitric acid, rigid plastic IBCs and composite IBCs with a rigid plastic inner receptacle are authorized for two years from the date of IBC manufacture. The components may be placed in the same outer packaging provided they will not interact dangerously in the event of leakage. quantity (RQ)", contains the reportable quantity (RQ), in pounds and kilograms, for each hazardous substance listed in Column 1 of TABLE 1. They must be classified in accordance with the procedure as set out in the Manual of Tests and Criteria, part III, section 39 (IBR, see 171.7 of this subchapter). The requirements of 172.203(m) and 172.505 of this subchapter do not apply. full text search results A combination packaging consisting of a 4G fiberboard box with inner receptacles of glass or earthenware; b. in such a manner as to prevent short circuits, accidental operation, and significant movement relative to the cargo transport unit under the shocks, loadings, and vibrations normally incident to transport. 43 The membrane filters, including paper separators and coating or backing materials, that are present in transport, must not be able to propagate a detonation as tested by one of the tests described in the UN Manual of Tests and Criteria, Part I, Test series 1(a) (IBR, see 171.7 of this subchapter). Cargo and portable tanks must have a design pressure of at least 1,207 kPa (175 psig). (i) These provisions apply to the transportation of hazardous materials in UN portable tanks. TP36 For material assigned this portable tank special provision, portable tanks used to transport such material may be equipped with fusible elements in the vapor space of the portable tank. Packages containing mixtures with not less than 90% by mass, of phlegmatizer need not bear a POISON subsidiary risk label. B67 All valves and fittings must be protected by a securely attached cover made of metal not subject to deterioration by the lading, and all valve openings, except safety valve, must be fitted with screw plugs or caps to prevent leakage in the event of valve failure. This training must be documented in training records required by 172.704(d). Large Packagings are authorized for the Packing Group III entries of specific proper shipping names when either special provision IB3 or IB8 is assigned to that entry in the 172.101 Table. Dry sodium cyanide or potassium cyanide is also permitted in siftproof, water-resistant, fiberboard IBCs when transported in closed freight containers or transport vehicles. The unintended errors are summarized below. All openings must be closed with gasketed blank flanges or vapor tight threaded closures. The examination and testing of each lighter design must be performed by a person authorized by the Associate Administrator under the provisions of subpart E of part 107 of this chapter, as specified in 173.308(a)(4). N12 Plastic packagings are not authorized. Bulk packagings must have exterior heating coils fusion welded to the tank shell which have been properly stress relieved. Pressure relief devices shall be designed to prevent the entry of foreign matter, the leakage of liquid and the development of any dangerous excess pressure. The letter Z shown in the marking code for composite IBCs must be replaced with a capital code letter designation found in 178.702(a)(2) of this subchapter to specify the material used for the other packaging. Component cells of the battery must be of a type proved to meet the respective testing requirements of the Manual of Tests and Criteria, part III, subsection 38.3 (IBR, see 171.7 of this subchapter). TP20 This hazardous material must only be transported in insulated tanks under a nitrogen blanket. contact the publishing agency. These provisions apply only to transportation by water: W1 This substance in a non friable prill or granule form is not subject to the requirements of this subchapter when tested in accordance with the UN Manual of Test and Criteria (IBR, see 171.7 of this subchapter) and is found to not meet the definition or criteria for inclusion in Division 5.1.

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